| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With medical stone, wollastonite, kaolin, red metal and stone, bentonite and polyhalite make carrier after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add surfactant myristyl tributyl ammonium chloride and activation process is carried out under ul-trasonic irradiation, then carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), three (2, 2, 6, 6 tetramethyls 3, 5 heptadione acid) gadolinium, it is hydrated three acetic acid terbiums, trifluoromethayl sulfonic acid thulium (III), catalytic active center predecessor titanocenes ring substituted salicylic acid complex, zinc lactate and two thiocyanatos silver（I）Sour potassium, the ammino palladium of dichloro four, hydro-thermal reaction is carried out under the effect of emulsifying agent octadecyldimethyl hydroxypropyl ammonium chloride, and drying removes after moisture that calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |