| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With erionite, garnet, diatom is pure, kyanite, shepardite and serpentinite make carrier, carrier is after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, surfactant dodecyltrimethyl is added after ul-trasonic irradiation activation process, activated carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), three (hexafluoroacetylacetone) yttrium (III) dihydrates, 1, 1, 1 trifluoroacetylacetone (TFA) neodymium, it is hydrated three acetic acid terbiums, catalytic active center component predecessor titanocenes ring substituted salicylic acid complex, pyruvic acid isonicotinoyl hydrazone vanadium, zinc lactate, six nitroso rhodium trisodiums, hydro-thermal reaction is carried out under the effect of the hydroxypropyl dichloride ammonium of ten alkyl dimethyl N ' trimethyls of emulsifying agent N 2, drying removes moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |