| abstract |
The present invention relates to a kind of preparation method of ozone Heterogeneous oxidation solid catalyst, category environmental protection and technical field of chemical engineering catalysts.With medical stone, wollastonite, dolomite, calcite, illite and raphite make carrier, carrier is after lithium hypochlorite and double (acetylacetone,2,4-pentanedione) beryllium reamings, add myristyl tributyl ammonium chloride and activation process is carried out under ul-trasonic irradiation, then activated carrier in hydrothermal reaction kettle with composite mineralizer borax and potassium sulfate, catalytic activity auxiliary agent predecessor catalytic activity auxiliary agent predecessor isopropyl scandium oxide (III), three (4, 4, (2 thiophene) 1 of 4 trifluoro 1, 3 diacetyl) europium, ten water holmium oxalates, three [N, double (trimethyl silane) amine of N] erbium, catalytic active center component predecessor titanocenes ring substituted salicylic acid complex, zinc lactate, zirconium carbonate ammonium, tetrachloro two is hydrated iridium, hydro-thermal reaction is carried out under the effect of N octadecyldimethyl N ' thmethylpropyl dichlorides ammonium, drying removes moisture, calcination obtains ozone Heterogeneous oxidation solid catalyst in Muffle furnace. |