http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106977545-B
Outgoing Links
Predicate | Object |
---|---|
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F9-655345 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F9-4075 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F9-4056 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-6553 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-40 |
filingDate | 2017-04-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2019-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2019-04-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-106977545-B |
titleOfInvention | A kind of 3- sweet-smelling formacyl difluoro methylene allyl phosphonic acid ester and its synthetic method |
abstract | The invention discloses a kind of 3- sweet-smelling formacyl difluoro methylene allyl phosphonic acid ester and its synthetic method, shown in the 3- sweet-smelling formacyl difluoro methylene allyl phosphonic acid ester structure formula such as following formula (1): Wherein: substituent R 1 , R 2 For alkyl or R 1 R 2 It is connected to C 3 ‑C 6 Alkylidene, Ar are phenyl, substituted phenyl or heteroaryl.Compared with the existing technology; the method of the present invention is a kind of efficient, simple, high regio-selective synthesis 3- sweet-smelling formacyl difluoro methylene allyl phosphonic acid ester method; this method simplicity, mild condition, good yields; the yield of object can reach 65%-85%; regioselectivity is high, occurs in connection 2,3 double bonds of alkene to hydroacylation reaction selectivity; acyl group is added in connection alkene middle carbon, and palladium catalyst is cheap and easy to get in the method. |
priorityDate | 2017-04-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 46.