http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106977470-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D277-18 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D277-18 |
| filingDate | 2017-03-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2019-11-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2019-11-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-106977470-B |
| titleOfInvention | A kind of synthetic method of visible light-catalyzed 2-iminothiazoline derivatives |
| abstract | A kind of synthetic method of 2-iminothiazoline derivatives of visible light catalysis, described synthetic method is: in reaction solvent, with the saturated aziridine shown in formula (II) and formula (III) shown The isothiocyanate compound is a raw material, and the 2-iminothiazoline derivative shown in formula (I) is obtained by reacting under nitrogen protection, illumination conditions and the action of a photocatalyst and an oxidant; the photocatalyst is selected from Any of the following: Ru(bpy) 3 (BF 4 ) 2 , Ru(bpy) 3 Cl 2 ยท6H 2 O, Ru(bpy) 3 (PF 6 ) 2 , Ir(ppy) 3 , [Ir(ppy) 2 bpy]BF 4 , [Ir(ppy) 2 bpy]PF 6 , Ru(bpz) 3 (PF 6 ) 2 , Ir[dF(CF 3 )ppy] 2 (dtbbpy)PF 6 , eosinY; From any of the following: tetrafluoroborate phenyldiazonium salt, ceric ammonium nitrate, 1-chloromethyl-4-fluoro-1,4-diazonium bicyclic 2.2.2 octane bis (tetrafluoroborate) salt . The method of the invention has the advantages of mild reaction conditions, wide substrate range, green environmental protection, high atom economy, step economy and the like. |
| priorityDate | 2017-03-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 92.