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filingDate 2017-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2020-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2020-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-106866986-B
titleOfInvention Pd/Ln dissimilar metal organic framework and preparation method and application thereof
abstract The invention discloses a Pd/Ln dissimilar metal organic framework and a preparation method and application thereof, and relates to a chemical functional material and a preparation method and application thereof 3 ) 3 ·6H 2 O or Eu (NO) 3 ) 3 ·6H 2 O or Tb (NO) 3 ) 3 ·6H 2 O or Dy (NO) 3 ) 3 ·6H 2 O, potassium tetrachloropalladate K 2 PdCl 4 The azacyclo-carboxylic acid 1,1 '-di (p-carboxyl benzyl) -2,2' -diimidazole ligand is used as a reaction precursor, and is synthesized by a solvothermal method, and the molecular formula of the compound is [ H 3 O]n[LnPd 2 [L] 2 Cl 4 ]n, wherein Ln represents Sm or Eu or Tb or Dy; l is 1,1 '-di (p-carboxybenzyl) -2,2' -bisimidazole. The catalyst has novel structure, simple synthesis, high yield and stability in air and water. The yield is more than 99%. The catalyst can be reused in ethanol and water-ethanol solvent by centrifugal separation; can be separated by adjusting the pH value in the aqueous solution and recycled.
priorityDate 2017-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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