http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106866986-B
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-824 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2231-4205 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C1-321 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1691 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-68 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G83-008 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C15-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C1-32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G83-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-784 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-68 |
filingDate | 2017-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2020-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2020-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-106866986-B |
titleOfInvention | Pd/Ln dissimilar metal organic framework and preparation method and application thereof |
abstract | The invention discloses a Pd/Ln dissimilar metal organic framework and a preparation method and application thereof, and relates to a chemical functional material and a preparation method and application thereof 3 ) 3 ·6H 2 O or Eu (NO) 3 ) 3 ·6H 2 O or Tb (NO) 3 ) 3 ·6H 2 O or Dy (NO) 3 ) 3 ·6H 2 O, potassium tetrachloropalladate K 2 PdCl 4 The azacyclo-carboxylic acid 1,1 '-di (p-carboxyl benzyl) -2,2' -diimidazole ligand is used as a reaction precursor, and is synthesized by a solvothermal method, and the molecular formula of the compound is [ H 3 O]n[LnPd 2 [L] 2 Cl 4 ]n, wherein Ln represents Sm or Eu or Tb or Dy; l is 1,1 '-di (p-carboxybenzyl) -2,2' -bisimidazole. The catalyst has novel structure, simple synthesis, high yield and stability in air and water. The yield is more than 99%. The catalyst can be reused in ethanol and water-ethanol solvent by centrifugal separation; can be separated by adjusting the pH value in the aqueous solution and recycled. |
priorityDate | 2017-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 53.