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filingDate 2017-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2019-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2019-07-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-106832095-B
titleOfInvention A kind of electrochemical regulating and controlling atom transfer radical polymerization method under alkali effect
abstract The invention discloses the electrochemical regulating and controlling atom transfer radical polymerization methods under a kind of effect of alkali, this method is in the case where electrochemical action, under conditions of not using any ligand, alkali compounds is added, mix the reaction raw materials including monomer, catalyst, initiator, electrolyte and solvent, so that so that monomer is carried out atom transition free radical polymerization reaction generates corresponding polymer.The present invention is by improving reaction raw materials used by electrochemistry atom transition free radical polymerization reaction and reaction condition etc., alkali compounds is added during electrochemistry atom transition free radical polymerization reaction and promotes polymerization reaction, can be reduced or do not use the use of ligand and reducing agent.Therefore, the present invention can effectively solve the problem that storage and the processing difficult problem of lower valency transition-metal catalyst used in existing Atom Transfer Radical Polymerization System, and expensive, the disadvantages of being more toxic and is volatile present in ligand and reducing agent can be overcome, reduce the extent of damage and reaction cost to environment.
priorityDate 2017-02-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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