http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106800575-A

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filingDate 2016-12-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1f3b1522f7dc7b1f571a230124ba153a
publicationDate 2017-06-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-106800575-A
titleOfInvention Broadband visible light absorption triplet photosensitizer and its preparation method and application
abstract A triplet photosensitizer based on broadband visible light absorption, which has the following structure: Compared with the prior art, the present invention has the remarkable advantage that a rhodium porphyrin-azafluoroboron dipyrrole {Rh(ttp)-aza-BODIPY} compound is synthesized through the axial connection of Rh-C bonds. On the one hand, this synthesis design can make the d orbital of the metal participate in the transition and transfer process of electrons as the frontier orbital, increase the intersystem crossing, and improve the efficiency of the triplet state. At the same time, the absorption spectra of the two fluorescent molecules are organically combined to obtain A triplet photosensitizer with strong broadband absorption in the visible region. The synthesis design is not restricted by many factors of resonance energy transfer, and the operation is simple and flexible. The absorption spectrum of the synthesized triplet photosensitizer covers from 380nm to 750nm, regardless of the excitation wavelength in its absorption spectrum, it can effectively generate singlet oxygen, so the obtained photosensitizer can efficiently use the energy of the composite light source, such as the sun Light, the superior performance makes it have a good application prospect. The invention discloses its preparation method.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/KR-102009601-B1
priorityDate 2016-12-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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