| abstract |
The invention discloses a kind of electrochemical regulating and controlling atom transfer radical polymerization method of nontoxic part, the method is in the case of electrochemical action, under conditions of poisonous part is not used, make to be mixed including the reaction raw materials including monomer, catalyst, initiator, electrolyte and solvent, so that monomer carries out atom transition free radical polymerization reaction generates corresponding polymer.The present invention is improved by reaction raw materials and reaction condition for being used to atom transition free radical polymerization reaction etc., apply electrochemical action during atom transition free radical polymerization reaction, can effectively solve the problem that storage and the difficult treatment problem of the lower valency transition-metal catalyst used in existing Atom Transfer Radical Polymerization System, and the shortcomings of poisonous part and expensive, larger toxicity and volatility existing for reducing agent can be overcome, reduce the extent of damage and reaction cost to environment. |