http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106601917-A

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publicationDate 2017-04-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-106601917-A
titleOfInvention A kind of lead-free organic-inorganic cation co-hybridized perovskite material and its thin film preparation method
abstract The invention discloses a preparation method of a lead-free organic-inorganic cation hybrid perovskite material and a film thereof. The lead-free organic-inorganic cation hybrid perovskite material is composed of organic cations such as methylamino or ethylamino and Rb Or Cs and other inorganic cations co-hybridized BiI3, and the lead-free organic-inorganic cations co-hybridized perovskite film was prepared by magnetron sputtering. The invention relates to the field of solar photoelectric materials and semiconductor materials, and replaces Pb with Bi to become the central ion of the perovskite material to avoid potential pollution of the perovskite material to the environment. In addition, the perovskite obtained by co-hybridization of Bi and organic and inorganic cations The material has a lower band gap, which is conducive to electronic transition and improves the photoelectric conversion efficiency.
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