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publicationDate 2017-04-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-106573991-A
titleOfInvention Method for producing carboxymethyl cellulose salt for electrode of nonaqueous electrolyte secondary battery, electrode for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery
abstract The object of the present invention is to provide a carboxymethylcellulose salt for an electrode of a non-aqueous electrolyte secondary battery, which can prevent defects such as streaks and pinholes on the coated surface of the electrode and can combine excellent adhesion to a current collector Strength or adhesive strength between active substances. A production method comprising the following steps: (1) an alkali cellulose reaction step, which uses a mixed solvent with a mixing ratio (mass ratio) of alcohol with a carbon number of 3 or less and water of 75:25 to 95:5, and The concentration of alkali relative to water is 25% to 40% by mass; (2) etherification reaction step, which is carried out under the excess of alkali, and the excess of alkali is 0.2 mole per anhydroglucose unit of the cellulose ~0.5 moles; (3) neutralization step, after the etherification reaction is finished, adding acid to adjust the pH value of the reaction mixture to 6.0 ~ 8.0; and (4) heating step, after the neutralization step is finished , removing the mixed solvent, adding a base to adjust the pH of the reaction mixture to 8.0-9.0, and then performing heat treatment at 40°C-70°C for 30 minutes-120 minutes.
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