http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106397345-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-13 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D249-12 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D249-12 |
| filingDate | 2016-09-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2019-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2019-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-106397345-B |
| titleOfInvention | A kind of 3-carboxy-1,2,4-triazole type cobalt complex and its in-situ synthesis method |
| abstract | The invention discloses a 3-carboxy-1,2,4-triazole cobalt complex and an in-situ synthesis method thereof. The chemical formula of the cobalt complex is [Co 2 (L 3 ) 2 (H 2 O) 2 ] (HL 3 =3-carboxy-1,2,4-triazole). Its in-situ synthesis method comprises the following steps: respectively take by weighing 0.04-0.05 g two (5-thione-1,2,4-triazole) methane (L 1 ) and 0.10-0.15g CoCl 2 6H 2 Mix O in 7-8mL water, then add 1-1.5mL DMF, stir at room temperature for 30-35min; transfer the above solution into a 25 mL polytetrafluoroethylene reactor, place it in a constant temperature oven at 130-140 ℃ for 60-80 After one hour, the temperature was lowered to room temperature at 5°C per hour, filtered, and washed with anhydrous methanol to obtain red-brown single-crystal bulk crystals. The in-situ synthesis of the complex of the present invention overcomes the shortcomings of the solvent method, and has the advantages of easy availability of raw materials, low cost, simple process and the like. |
| priorityDate | 2016-09-12-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 24.