| abstract |
The invention provides black phosphorus modified by titanium ligands and its preparation method and application. The black phosphorus modified by titanium ligands is a complex of black phosphorus and titanium ligands, and the titanium ligands have the formula (I) The structure shown: In formula (I), R 1 includes C 1-6 alkyl or phenyl, and said phenyl is optionally further replaced by 0-5 independently halogen atoms, C 1-6 alkyl, nitro, hydroxyl, amino, C 1-3 alkoxy substituted; said C 1-6 alkyl or C 1-3 alkoxy is optionally further 0-3 independently halogen atoms, nitro, hydroxyl, amino, methyl, Ethyl or n-propyl substitution. The titanium ligand-modified black phosphorus in the present invention is not easily oxidized without changing the inherent properties of the black phosphorus, and its anti-oxidation ability is greatly enhanced. |