http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106279288-B

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classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02W10-37
classificationIPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C02F101-30
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-94
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C02F1-30
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22
filingDate 2015-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-12-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2018-12-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-106279288-B
titleOfInvention The preparation and application of six core bismuth cluster compounds
abstract The present invention is prepared for six core bismuth cluster complex of tetrazoleacetic acid by mild aqueous process.Method is: the concentration of tetrazoleacetic acid is 2.6g/L~4.3g/L, molar ratio with bismuth nitrate is 4: 1~5: 1, it is dissolved in 30~50 milliliters of water, after 80~100 DEG C are reacted 1~2 hour, it is separately added into lanthanum nitrate, manganese nitrate and copper nitrate in the solution, after reacting 1~2 hour again, products therefrom distilled water, ethyl alcohol, which clean, to be air-dried, and three kind of six core bismuth cluster complex, complex 1 are as follows: { [Bi are obtained 6 (tza) 5 (NO 3 )(OH) 7 O].(OH) 2 } n ;Complex 2 are as follows: { [Bi 6 (tza) 5 (NO 3 ) 2 (OH) 5 O 2 ]·(OH)} n ;Complex 3 are as follows: { [Bi 6 (tza) 5 (NO 3 ) 2 (OH) 5 O 2 ].(OH) 2 } n ;By this three kinds of complexs and octogen (HMX) 1: 3 ground and mixed in mass ratio, its thermal stability is surveyed with thermogravimetric and differential scanning technology (DSC-TG) and HMX Catalytic Thermal Decomposition is acted on.The result shows that: complex 3 is most stable, and 1,2,3 couples of HMX of complex have apparent catalytic action;In addition, complex 3 is 2 in pH, Methyl Orange in Wastewater photocatalytic degradation can be made colourless under ultraviolet light.
priorityDate 2015-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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