http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106279288-B
Outgoing Links
Predicate | Object |
---|---|
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02W10-37 |
classificationIPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C02F101-30 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-94 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C02F1-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 |
filingDate | 2015-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2018-12-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2018-12-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-106279288-B |
titleOfInvention | The preparation and application of six core bismuth cluster compounds |
abstract | The present invention is prepared for six core bismuth cluster complex of tetrazoleacetic acid by mild aqueous process.Method is: the concentration of tetrazoleacetic acid is 2.6g/L~4.3g/L, molar ratio with bismuth nitrate is 4: 1~5: 1, it is dissolved in 30~50 milliliters of water, after 80~100 DEG C are reacted 1~2 hour, it is separately added into lanthanum nitrate, manganese nitrate and copper nitrate in the solution, after reacting 1~2 hour again, products therefrom distilled water, ethyl alcohol, which clean, to be air-dried, and three kind of six core bismuth cluster complex, complex 1 are as follows: { [Bi are obtained 6 (tza) 5 (NO 3 )(OH) 7 O].(OH) 2 } n ;Complex 2 are as follows: { [Bi 6 (tza) 5 (NO 3 ) 2 (OH) 5 O 2 ]·(OH)} n ;Complex 3 are as follows: { [Bi 6 (tza) 5 (NO 3 ) 2 (OH) 5 O 2 ].(OH) 2 } n ;By this three kinds of complexs and octogen (HMX) 1: 3 ground and mixed in mass ratio, its thermal stability is surveyed with thermogravimetric and differential scanning technology (DSC-TG) and HMX Catalytic Thermal Decomposition is acted on.The result shows that: complex 3 is most stable, and 1,2,3 couples of HMX of complex have apparent catalytic action;In addition, complex 3 is 2 in pH, Methyl Orange in Wastewater photocatalytic degradation can be made colourless under ultraviolet light. |
priorityDate | 2015-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 46.