http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106279221-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B2200-13 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P70-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02E60-50 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F5-003 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/H01M8-1081 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F5-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01M8-1081 |
| filingDate | 2016-07-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2018-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2018-07-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-106279221-B |
| titleOfInvention | A kind of synthetic method of high proton conductive metal organic framework material |
| abstract | The invention discloses a kind of synthetic method of high proton conductive metal organic framework material, the specific steps are：Into the aqueous solution containing oxalic acid and monovalence organic amine salt, the aqueous solution of trivalent metal salt and monovalence organic amine salt is added dropwise, is stirred to react 10 60 minutes；Either trivalent metal oxide, acid and water are mixed, after solution clarification, pH value of solution=2~4 is adjusted with organic amine, then be added into the aqueous solution containing oxalic acid and monovalence organic amine salt, is stirred to react 10 60 minutes；Then it filters, precipitates, wash, it is dry, obtain target product；Synthesized material structure general formula is：(HA)[Ln(C 2 O 4 ) 2 (H 2 O)]·3H 2 O.Synthesized compound belongs to micropore MOF materials, has very high thermal stability (being more than 330 DEG C) and excellent proton conductivity of phosphoric acid.Reaction raw materials used by this method are cheap and easy to get, and reaction condition is mild, simple for process, and yield is high, at low cost, do not use any organic solvent, belong to green syt, be very suitable for large-scale industrial production. |
| priorityDate | 2016-07-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 41.