| abstract |
The invention discloses controllable method for preparing and the application of a kind of Modified with Polar Monomer hypercrosslinked polymeric resin.The preparation method of Modified with Polar Monomer hypercrosslinked polymeric resin is by suspension copolymerization by 4 vinyl benzyl chloride monomers, vinyl imidazole class polar monomer, divinylbenzene crosslink agent etc., obtains presoma resin；Gained presoma resin, under Louis acid catalysis effect, carries out Friedel Crafts reaction, has obtained Modified with Polar Monomer hypercrosslinked polymeric resin.By changing 4 vinyl benzyl chloride monomers, the percentage composition of divinylbenzene crosslink agent, the hypercrosslinked polymeric resin of a series of Different Pore Structures and opposed polarity can be prepared；This resinoid structural controllability imparts the adsorptive selectivity that they are different with the armaticity Organic substance of size to opposed polarity.Additionally, the controllable synthesis method of this Modified with Polar Monomer hypercrosslinked polymeric resin is simple, low cost, can industrialized production. |