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http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C315-00
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C315-00
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C317-44
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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-26
filingDate 2016-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2018-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-106083665-B
titleOfInvention A method of using aryl sulfonyl benzaldehyde hydrozone to cyclopropane compound open loop
abstract It is that nucleopilic reagent is done using aryl sulfonyl benzaldehyde hydrozone for starting material with 1,1 dibasic acid esters, 2 aryl cyclopropane compound the invention discloses a kind of method cyclopropane compound occurring using aryl sulfonyl benzaldehyde hydrozone ring-opening reaction;Under trifluoromethanesulfonic acid metal class and halogenated metal class two-way Lewis acid catalyst action, the ring-opening reaction of cyclopropane and hydrazone occurs in benzene kind solvent, reaction temperature is 25~50 DEG C, obtains the fragrant multifunctional dough sulfone class product of fat.Reaction process of the present invention is easy to operate, and synthetic method has extensive universality, can get higher yield for the dibasic acid esters cyclopropane and aryl sulfonyl benzaldehyde hydrozone of different structure.
priorityDate 2016-06-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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