http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-106046388-B
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-145 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G83-008 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G83-00 |
filingDate | 2016-05-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2018-11-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2018-11-06-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-106046388-B |
titleOfInvention | A kind of furancarboxylic acid class rare earth neodymium metal-organic framework luminescent material and its synthetic method |
abstract | The invention belongs to technical field of material chemistry, being related to a kind of furancarboxylic acid class rare earth neodymium metal-organic framework luminescent material and its synthetic method, the compound has near-infrared fluorescent characteristic and the ultraviolet-visible characteristics of luminescence.A kind of furancarboxylic acid class rare earth neodymium metal-organic framework luminescent material, chemical general formula are:{[Nd 2 (H 2 O) 3 (FDA) 3 (CH 3 OH)]·CH 3 OH} n , in formula:FDA is furans -2,5- dicarboxylic acids, CH 3 OH is methanol, and n is expressed as 1 and arrives just infinite natural number.Topological structure is four node novel topological structures of one 3,3,5,6- connection, and point symbol is (4.5.6) 2 (4.6 2 ) 2 (4 2 .5 4 .6 2 .7 2 ) 2 (5 2 .6 6 .7 4 .9 2 .10).By neodymium hydroxide and furan dicarboxylic acid with the amount molar ratio 1 of substance:2 mixing, it is 3 that methanol, which is then added, with water volume ratio:1 8~10mL of mixed solvent obtains mixed solution, and 2min is stirred under room temperature;Reaction kettle equipped with above-mentioned mixed solution is put into baking oven, constant temperature 72h at 120 DEG C, then passes through and room temperature is at the uniform velocity down to 2 DEG C/h.With good luminosity and stability, and preparation process simple and efficient, of low cost, favorable reproducibility. |
priorityDate | 2016-05-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 27.