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filingDate 2016-03-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2019-02-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2019-02-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-105854943-B
titleOfInvention The preparation method of rare earth modified heteropolyacid catalyst and the preparation method of biodiesel
abstract The present invention provides a kind of preparation method of rare earth modified heteropolyacid catalyst and the preparation methods of biodiesel.The preparation method of the rare earth modified heteropolyacid catalyst, the following steps are included: step S1, being that 0.01~0.05:0.08~0.40:0.45~2.25:0.0008~0.004:0.001~0.0025 metal precursor, alcohol, strong acid, the compound of rare earth M and heteropoly acid are stirred dispersion and obtain mixed solution by molar ratio, M is that lanthanum, cerium, praseodymium, neodymium, promethium and samarium are any one or more of;Step S2, the mixed solution is stood to formation gel;Step S3, the gel is dried, obtains the rare earth modified heteropolyacid catalyst containing M-O key.By utilizing the compound of rare earth M modified to heteropoly acid under strong acid solution existence condition, so that in rare earth M and heteropoly acid 0 between form stable M-0 key, and M-0 can be as acid activated centre, to obtain a kind of catalyst with high catalytic activity and stability.
priorityDate 2016-03-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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