http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-105646593-B
Outgoing Links
Predicate | Object |
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classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-185 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01N2021-6495 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01N2021-7786 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-1014 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-1007 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-1092 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K2211-1029 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01N21-78 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F15-0033 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/G01N21-64 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01N21-78 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/G01N21-64 |
filingDate | 2016-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2018-06-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2018-06-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-105646593-B |
titleOfInvention | Neutral iridium complex containing thiophene group and its preparation method and application |
abstract | The invention relates to a neutral iridium complex containing a thiophene group and its preparation method and application. The structural formula of the complex is as follows. Its preparation method comprises the following steps: under anhydrous and anaerobic operation, dissolving the potassium salt of bis-{bis[2-(2-thiophene)pyridine] iridium dichloride} and bis(diphenylphosphonic acid) amine In a solvent, react at 120-140°C for 12-24 hours, cool, filter, purify by SiO 2 column chromatography, and then recrystallize to obtain a neutral iridium complex containing a thiophene group. The iridium complex in the present invention is a phosphorescent iridium complex containing a thiophene group and a novel auxiliary ligand bis(diphenylphosphonamide), which realizes selective recognition of higher sensitivity to Hg 2+ , and the complex synthesis steps It is relatively simple, has high luminous efficiency, and improves the accuracy of detection. |
priorityDate | 2016-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 46.