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filingDate 2016-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-06-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2018-06-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-105646593-B
titleOfInvention Neutral iridium complex containing thiophene group and its preparation method and application
abstract The invention relates to a neutral iridium complex containing a thiophene group and its preparation method and application. The structural formula of the complex is as follows. Its preparation method comprises the following steps: under anhydrous and anaerobic operation, dissolving the potassium salt of bis-{bis[2-(2-thiophene)pyridine] iridium dichloride} and bis(diphenylphosphonic acid) amine In a solvent, react at 120-140°C for 12-24 hours, cool, filter, purify by SiO 2 column chromatography, and then recrystallize to obtain a neutral iridium complex containing a thiophene group. The iridium complex in the present invention is a phosphorescent iridium complex containing a thiophene group and a novel auxiliary ligand bis(diphenylphosphonamide), which realizes selective recognition of higher sensitivity to Hg 2+ , and the complex synthesis steps It is relatively simple, has high luminous efficiency, and improves the accuracy of detection.
priorityDate 2016-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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