| abstract |
The invention relates to preparation of a porous integral material on the basis of a thiol-methacrylate click reaction. In particular, the preparation method includes the steps of: mixing a polyhedral oligomeric silsesquioxanes (POSS) reagent or an organic reagent containing a multi-methyl acrylate functional group, a multi-thiol crosslinking agent, a pore-forming solvent and a catalyst, dissolving the components under supersonic, and performing the thiol-methacrylate click reaction at certain temperature to prepare the porous integral material. The preparation method is simple and quick in operations and has strong universality, and can be used for prepare a series of different organic polymer integral materials and organic-inorganic hybrid integral materials. |