http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-104557500-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-782 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-563 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-784 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-76 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-813 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-792 |
| filingDate | 2013-10-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2016-05-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2016-05-18-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-104557500-B |
| titleOfInvention | A kind of method of synthetic alpha-alkyl ketone |
| abstract | The invention discloses a kind of method of synthetic alpha-alkyl ketone. In reaction vessel, add alkynes, [(IPr) AuCl], AgOTf, Isosorbide-5-Nitrae-dioxane and water, reactant mixture is 120 o Under C, microwave reaction is after 1 hour, cool to room temperature; Add wherein again [Cp*IrCl 2 ] 2 , alkali and alcohol, reactant mixture is 130 o Under C, microwave reaction is after 2 hours, cool to room temperature; Filter, rotary evaporation, except desolventizing, then separates by post, obtains target compound. The industrial chemicals alkynes of the present invention from easily obtaining, water and alcohol set out, in the presence of gold and iridium catalyst, the alpha-alkyl ketone obtaining, reaction only generates water as accessory substance; Therefore, this reaction meets the requirement of Green Chemistry, has vast potential for future development. |
| priorityDate | 2013-10-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 132.