http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-104513274-B
Outgoing Links
Predicate | Object |
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B53-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F19-00 |
filingDate | 2013-09-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2018-07-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2018-07-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-104513274-B |
titleOfInvention | A kind of chiral pincerlike compounds of P and its palladium complex |
abstract | The present invention relates to a kind of chiral pincerlike compounds of P(II)And its palladium complex(I)With their synthetic method.Palladium complex(I)(Wherein, X represents the alkyl that Cl, R represent hydrogen atom or carbon atom number is 1~4, and it is R configurations or S configurations simultaneously that the chirality of two P, which is,)Pass through compound(II)Complexation reaction with divalent palladium salt and synthesize.Palladium complex(I)(Wherein, X is selected from Br, I, OAc, OTf, BF 4 、‑SbF 6 Group)The palladium complex of Cl is represented by X(I)It is synthesized by anion exchange reaction.The palladium complex of the present invention(I)Chiral catalyst can be used as to be applied in a variety of asymmetric reactions, such as asymmetry Micheal additions, asymmetry Heck coupling reactions, asymmetry Suzuki Miyaura coupling reactions, asymmetric allylation. |
priorityDate | 2013-09-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 149.