http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-104478936-B
Outgoing Links
Predicate | Object |
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-03 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C43-23 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F9-92 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C201-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B41-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C37-20 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C33-48 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-40 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C39-19 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D307-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C205-19 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C41-30 |
filingDate | 2014-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2016-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2016-06-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-104478936-B |
titleOfInvention | The preparation and application of bi triphenyl antimony organic (V) title complex of a kind of ionic |
abstract | The present invention provides a kind of bi triphenyl antimony organic (V) the complex preparation method of ionic and the synthetic method of the allyl alcohol compounds for catalysis thereof, described title complex is cationic organic stibium complex, wherein, in this title complex, two antimony atoms are joined by Sauerstoffatom bridge, display pentavalent. Each antimony atoms and a water molecule coordination, whole antimony organic cationic moiety forms ionic linkage with corresponding negatively charged ion. Described synthetic method, taking above-mentioned bi triphenyl antimony organic (V) title complex as catalyzer, using conventional organic solvent as reaction solvent, taking aldehyde and tetra allylic tin as raw material, is reacted. This synthetic method is that the preparation of allyl alcohol compounds opens new low cost " green " approach, its advantage is: the selectivity of target product and product rate height, catalyzer can reuse, product can obtain corresponding ketone by simple column chromatography for separation, whole reaction and separation processes process operation is simple, environmental protection. |
priorityDate | 2014-12-11-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 96.