http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-104327112-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-22 |
| filingDate | 2014-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2017-04-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2017-04-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-104327112-B |
| titleOfInvention | Dumbbell shaped methyl cup [4] aromatic hydrocarbons organotin oxygen bunch complex and preparation method thereof |
| abstract | A kind of dumbbell shaped methyl cup [4] aromatic hydrocarbons organotin oxygen bunch complex and preparation method thereof, belongs to technical field of chemistry, and complex is following chemical formula：[(Bu 2 Sn) 2 ( μ 3 ‑O)(L)(EtO)] 2 2EtOH, wherein L ‑ For methyl cup [4] aromatic carboxylic acid's anion ligand of deprotonation.N BuSn (O) OH and part HL and toluene and alcohol mixeding liquid are heated to reflux into 8 hours in Dean-Stark device, the water generated in dereaction is removed by azeotropic distillation, then solution decompression distillation is obtained into white solid, is recrystallized with the mixed solution of chloroform and ethanol at room temperature and obtained final product.The complex that the present invention is provided is to CH 2 Cl 2 Methyl red (MR) dyestuff in solution shows sensitive recognition capability.The fluorescence data of crystal prototype shows that this complex has fluorescence property, can be applied in material science as fluorescent material. |
| priorityDate | 2014-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 37.