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filingDate 2014-06-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-02-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2016-02-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-104016903-B
titleOfInvention Thio diene nickel title complex and its production and use
abstract Thio diene nickel title complex and its production and use, belongs to organic synthesis field, have employed following technical scheme: thio diene nickel title complex, and the general formula of described title complex is:n whereinn r is Cn 6 ~ Cn 20 straight or branched alkyl, or be Cn 6 ~ Cn 20 straight or branched alkoxyl group.The preparation process of this title complex is: by compoundn at organic solvent dissolution, then with oxalyl chloride (Cn 2 on 2 cln 2 ) acylation reaction, the adjacent dione compounds of the product obtained is at Pn 2 sn 5 thio diene nickel title complex is obtained by reacting with continuing under nickelous chloride effect.Preparation method of the present invention is simple, mild condition, obtained thermal analysis is good, not easily be separated, there is in near-infrared region very high photoabsorption coefficient, the effect of prepared spectral filter in near-infrared laser protection is fine, be particularly suitable for 1064nm lasing safety, the dual nature of the visuality that simultaneously the present invention also has a visible region and lasing safety compatibility mutually.
priorityDate 2014-06-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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