http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103992231-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C217-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-56 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-74 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C213-02 |
| filingDate | 2014-05-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2016-02-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2016-02-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-103992231-B |
| titleOfInvention | A kind of method of synthesizing triaryl amine |
| abstract | The invention discloses a kind of method of synthesizing triaryl amine, namely with molecular formula for [(ArNCHn 2 cHn 2 nAr) CH] [FeCln 4 ] ionic iron (III) title complex (wherein Ar=3,5-bis--[C (CHn 3 )n 3 ]-2-(OH)-Cn 6 hn 2 ) be catalyzer, under the existence of lithiumbromide, with diaryl-amine, ethylmagnesium bromide, aryl bromide or chlorinated aromatic hydrocarbons for Material synthesis triaryl amine.The method of structure triaryl amine provided by the invention has clear and definite structure and the ionic iron of air-stable (III) title complex is catalyzer, overcomes the oxidizable or unfavorable factor such as easy deliquescence and assorted metal interference of the catalyzer directly brought for catalyzer with iron or iron trichloride; Secondly, chlorinated aromatic hydrocarbons cheap and easy to get is introduced in this synthetic method by method provided by the invention first, the consumption of catalyzer and lithiumbromide is also only 0.3mol% and 10mol% of halogenated aryl hydrocarbon respectively, compared with the synthetic method of bibliographical information, there is higher catalytic efficiency and wider substrate applicability. |
| priorityDate | 2014-05-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 66.