| abstract |
The invention discloses high-strength hollow glass beads, comprising the chemical components: 71-76.5% of SiO2, 1.5-2% of Al2O3, 4.5-5% of B2O3, 2.5-3% of Li2O, 0.2-0.5% of SO3, 5.5-6% of Na2O, 2.3-3.5% of BaO, 4.5-6% of CaO4 and 2.5-3% of P2O5, wherein the density is 0.4-0.8g/cm<3>, the compressive strength is 30-130MPa, the particle size is smaller than or equal to 80mum, the floatage rate is greater than or equal to 90%, and the softening temperature is greater than or equal to 700 DEG C. The preparation method comprises the following steps: preparing BaO-Al2O3-SiO2-Li2O-SO3-CaO-P2O5-Na2O-B2O3 gel by adopting a sol-gel method for hydrolyzing a polyhydric alcohol salt; preparing silica nano powder by using an alkoxide hydrolysis-precipitation method; quickly dewatering and drying to synthesize spherical precursor powder after stirring, mixing and homogenizing in an atomization manner; carrying out vitrification sintering. The high-strength hollow glass beads are applicable to high-temperature and high-pressure fields with special requirements, such as underwater solid buoyancy materials and deep well cementing cement in oil drilling. |