http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103936537-B
Outgoing Links
Predicate | Object |
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-24 |
filingDate | 2014-04-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2015-10-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2015-10-28-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-103936537-B |
titleOfInvention | A kind of phenol of golden catalysis and the selectivity c h bond functionalization method of aniline |
abstract | The invention provides a kind of phenol of golden catalysis and the selectivity c h bond functionalization method of aniline, the present invention with phenol or amino benzenes compounds for raw material, with Phosphine ligands or Cabbeen for part, in organic solvent, under the effect of Au catalyst and silver salt, react with diazonium compound, in the contraposition of phenol or aniline structure or ortho position, C-H bond occurs and insert.It is few that the inventive method has catalyst levels, mild condition, substrate is suitable for the features such as wide, rapidly and efficiently can synthesize the method for the acetic acid methyl ester derivatives containing phenol or aniline structure, later stage modification can be carried out by this method to natural product or drug molecule (as estrone) simultaneously, or be used for synthesizing the molecule that some have physiologically active, have a good application prospect. |
priorityDate | 2014-04-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 75.