http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103833561-B
Outgoing Links
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-58 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C217-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B43-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C213-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C215-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-48 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D295-096 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D295-033 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C253-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D295-073 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D295-023 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-74 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C255-58 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 |
filingDate | 2014-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2016-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2016-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-103833561-B |
titleOfInvention | The N-arylation method of alkane amine |
abstract | The invention discloses a kind of N-arylation method of alkane amine, belong to chemosynthesis technical field.The method for additive with 2-pyridone oxime compound, using CuI as catalyzer, under the existence of alkali and solvent, makes alkane amine and aromatic compound Ar-X react, makes the N arylation of alkane amine.The method can promote the carrying out of N-arylation reaction well, and alkane aminated compounds and iodo aromatic compound nitrogen arylation reaction in aqueous is at room temperature carried out, and the nitrogen arylation reaction of bromo aromatic compound carries out at 65 DEG C; Simultaneously, this 2-pyridone oxime compounds can impel many compound generation Liv Ullmann linked reactions containing various functional group, especially can at room temperature efficient synthesis methylphenylamine and N ' accelerine compounds in the aqueous solution, there is the very wide substrate scope of application, have good application prospect. |
priorityDate | 2014-03-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 159.