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filingDate 2014-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2015-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_71dab7b7052ab6327a2ef03f5d3ecd4e
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publicationDate 2015-07-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-103755544-B
titleOfInvention Method for producing KA oil and adipic acid through oxidizing cyclohexane with air on basis of gas-liquid-solid heterogeneous reaction separation synchronization reactor
abstract The invention discloses a method for producing KA oil and adipic acid through oxidizing cyclohexane with air on the basis of a gas-liquid-solid heterogeneous reaction separation synchronization reactor, wherein the water-containing cyclohexane is added into the reactor, the reactor comprises a reaction tower and at least two constant temperature settlement towers communicated with the bottom of the reaction tower, and the reaction tower is internally provided with a gas phase area, an oxidization area and a gas outlet; the oxidization area and the constant temperature settlement towers are filled with the cyclohexane in the reaction, the air is introduced continuously from the bottom of the oxidization area and is in contact with the cyclohexane to carry out the oxidization reaction, meanwhile, a mixed phase of the produced KA oil, adipic acid and water settles and enters the bottom of the constant temperature settlement tower, the cyclohexane in the constant temperature settlement tower is pushed and goes up into the oxidization area to lead to the continuous reaction, the mixed phase continues to settle in the constant temperature settlement tower until the constant temperature settlement tower is fully filled with the mixed phase, then the reaction tower is switched to be communicated with the other constant temperature settlement tower filled with the cyclohexane, the operation is conducted on the constant temperature settlement towers alternatively to continuously produce the KA oil and adipic acid. The method is used to continuously produce the KA oil and the adipic acid with high percent of conversion and high selectivity, the production efficiency is improved, and the production cost is lowered.
priorityDate 2014-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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