http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103739417-B
Outgoing Links
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C237-30 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C227-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C225-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C221-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C217-84 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B43-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C213-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-52 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-51 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-47 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-45 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C231-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C229-60 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D213-73 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-10 |
filingDate | 2013-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2016-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2016-08-17-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-103739417-B |
titleOfInvention | A kind of method synthesizing aromatic primary amine in recirculated water phase system |
abstract | The invention discloses a kind of method synthesizing aromatic primary amine in recirculated water phase system, the method is with aryl halides and ammonia as raw material, using water as solvent, with alkali metal or the carbonate of alkaline-earth metal, fluoride, phosphate and hydroxide or the compound of corresponding alkali can be converted in water as alkali, with polyamines yl carboxylic acid and salt compounds thereof as part, copper source catalyst, catalysis aryl halides and ammonia is used to form aromatic primary amine.The present invention is using water as solvent, without using any phase transfer catalyst, and catalyst, part and reaction dissolvent water can recycle, effectively improve the environment friendly of reaction, more conform to the requirement of green chemistry, especially its wide application range of substrates, prepares aspect at natural product, medicine and pesticide and has broad prospects. |
priorityDate | 2013-09-29-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 146.