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filingDate 2013-11-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2017-02-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 2017-02-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-103647056-B
titleOfInvention SiOx based composite negative electrode material, preparation method and battery
abstract The invention relates to a high-capacity SiOx based composite negative electrode material, a preparation method and a battery, wherein the negative electrode material comprises a silicon oxide material, a carbon material and an amorphous carbon coating layer; the silicon oxide material is silicon oxide or silicon oxide material modified in a carbon coating manner; surfaces of carbon material particles are coated with the silicon oxide material. A preparation method of the high-capacity SiOx based composite negative electrode material comprises the steps of performing physical processing or carbon coating modification on a silicon oxide raw material, thus obtaining a micron-sized silicon oxide material; and then mechanically fusing, coating with a solid phase and sintering at a high temperature to obtain the high-capacity negative electrode material. Through the high-capacity SiOx based composite negative electrode material, the effect of uniform dispersing and coating of the micron-sized silicon oxide particles on the surfaces of the carbon material particles can be achieved by virtue of the combination of mechanical fusion and solid-phase coating processes. The silicon oxide particles are well dispersed on the surface of the carbon material particle; the strength of bonding between the silicon oxide particles and the carbon material particles is high; the recycling performance of the material can be greatly improved; and meanwhile, the high-capacity SiOx based composite negative electrode material is high in first efficiency (breaking through the theoretical efficiency of SiOx), low in expansion rate, long in service life, environmental-friendly, pollution-free and low in cost.
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