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filingDate 2013-10-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2014-11-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2014-11-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-103555236-B
titleOfInvention High-adhesiveness phenol aldehyde composite adhesive and preparation method thereof
abstract The invention belongs to the field of preparation of high-performance high polymer materials, and relates to a preparation method of a novel composite adhesive product, particularly a method for preparing a phenol aldehyde composite adhesive from an ionic liquid and a phenol aldehyde resin prepolymer by in-situ blending. The preparation method comprises the following steps: firstly synthesizing a phenol aldehyde resin prepolymer from raw materials phenol and formaldehyde in the presence of an alkali catalyst; by using an imidazole polyether ionic liquid with characteristic group as a modifier, heating, stirring under reflux, carrying out stage heating and temperature control, dehydrating under reduced pressure and the like to obtain the phenol aldehyde composite adhesive containing the imidazole polyether ionic liquid structure; and adding ethanol to regulate the viscosity of the composite adhesive to obtain the alcohol-soluble phenol aldehyde composite adhesive with acceptable viscosity. The method can further enhance the binding property and curing property of the phenol aldehyde adhesive, lower the free aldehyde content, and effectively solve the problems of low heat stability, deep color, high cracking tendency and the like in the phenol aldehyde adhesive.
priorityDate 2013-10-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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