http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103408601-B
Outgoing Links
Predicate | Object |
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classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B37-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F19-00 |
filingDate | 2013-07-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2015-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 2015-12-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-103408601-B |
titleOfInvention | There is heteronuclear bimetal complexes of catalysis suzuki reactive behavior and preparation method thereof |
abstract | There is heteronuclear bimetal complexes of catalysis suzuki reactive behavior and preparation method thereof, relate to a kind of metal complexes and preparation method thereof, three kinds of compounds in the present invention are all with 2,2 '-dipyridyl-5,5 '-dicarboxylic acid is part, central ion be respectively palladium ion and lanthanum ion, with cerium ion and with neodymium ion three groups of heteronuclear bimetals.By changing the mol ratio of each material, with the obtained three kinds of coordination compound Pd-L-La of hydro-thermal (solvent thermal) synthetic technology, Pd-L-Ce, Pd-L-Nd(L are part).Three kinds of novel complex structures are clear and definite, have fabulous catalytic activity to Suzuki linked reaction.Under this complex-catalyzed effect, there is Suzuki linked reaction in halogenated aryl hydrocarbon, synthesis polyene hydrocarbon, vinylbenzene and connection benzene derivate, this reaction is widely used in the preparations such as synthesis of natural product, medicine, liquid crystal, supramolecule, advanced material. |
priorityDate | 2013-07-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 31.