http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103254251-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F19-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-343 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C211-27 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C209-60 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B53-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-734 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-618 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C217-58 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C213-02 |
| filingDate | 2013-05-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2016-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2016-01-13-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-103254251-B |
| titleOfInvention | Containing dinaphthyl [1,2-b; 5,6-b '] π-allyl group iridium complex of cyclooctatetraene and chiral phosphine nitrogen skeleton, synthetic method and application |
| abstract | The invention provides and a kind of optically pure there is dinaphthyl [1,2-b; 5,6-b '] π-allyl group iridium complex of cyclooctatetraene and chirality phosphoramide skeleton, its synthetic method and the application of this complex compound in the asymmetric allylic substitution of metal iridium catalysis.This complex compound is with [Ir (dncot) Cl]n 2 , chiral phosphine nitrogen compound, substituted allyl carbonats compound, silver salt be that raw material carries out Reactive Synthesis, the raw material of the method is easy to get, reaction conditions gentle, product is easy to separating-purifying.Synthesized by the present invention, there is dinaphthyl [1,2-b; 5,6-b '] π-allyl group iridium complex of cyclooctatetraene and chirality phosphoramide skeleton, to air-stable.Effectively can be applied in the allyl substitution reaction of metal iridium catalysis, product can be obtained with high enantioselectivity and regioselectivity, greatly widen the substrate spectrum of this type of reaction. |
| priorityDate | 2013-05-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 92.