http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103232492-B
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_e5b801b9d9c27ae163b0e9a718942862 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F13-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01F1-42 |
| filingDate | 2013-02-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2015-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_92f642a93940cbdd6fa14508e277602a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_894a1813597d7ed5d8022db3b3f311e8 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a1936386785012897c2dbb700357cc60 |
| publicationDate | 2015-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-103232492-B |
| titleOfInvention | Mn binuclear magnetic single crystal complex and its preparation method and use |
| abstract | The invention relates to an Mn binuclear magnetic single crystal complex and its preparation method and use. The Mn binuclear magnetic single crystal complex has a molecular formula (1) of Mn<III>2(sap)2(MeOH)2(N3)2, wherein sap is salicylidene-2-ethanolamine and the crystal cell structure and composition are shown in the figure 1. The preparation method comprises that salicylidene-2-ethanolamine, Mn(NO3)2.6H2O and sodium azide are taken according to a stoichiometric ratio of (0.1-1): (0.1-1): (0.1-1.5) and are dissolved in alcohol having a temperature of 55 to 75 DEG C so that the Mn binuclear magnetic single crystal complex is obtained, wherein the dissolution steps comprise dissolving Mn(NO3)2.6H2O in alcohol to obtain a solution A, dissolving salicylidene-2-ethanolamine in alcohol to obtain a solution B, adding sodium azide into the solution A, stirring for 2.5 to 3.5h, adding the solution B into the mixture, sequentially stirring for 0.5 to 1.5h, carrying out filtration, standing the filtrate so that crystals are precipitated, washing the crystals, and drying the crystals in air. The Mn binuclear magnetic single crystal complex is a latent molecule-based magnetic material. The preparation method has simple processes and selects scientific ligands. The schiff base binuclear complex obtained by the preparation method has a clear and novel structure. The single crystal structure of the schiff base binuclear complex provides a novel basic scientific basis for a crystal database. |
| priorityDate | 2013-02-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 20.