http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103232316-B

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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_3bb71a8f2a224885c5bd38dac3bf9c0d
http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_18c61ebcd8852a1f2ff51e9125a76415
classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-52
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C13-277
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-38
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C2-46
filingDate 2012-11-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2015-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a0c0343d800f121a07b87d05843c3b5c
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d6a507fb7c70725111ce7559c694d775
publicationDate 2015-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-103232316-B
titleOfInvention Method for preparing 1,5,9-cyclododecatriene
abstract The invention provides a method for preparing 1,5,9-cyclododecatriene. The method comprises the steps that: in an organic solvent, a catalytic system composed of sesqui-alkyl aluminum chloride, TiX4 and at least one compound with a structure represented below is adopted, such that 1,3-butadiene is polymerized into 1,5,9-cyclododecatriene under catalysis. The X in the TiX4 is independently F, Cl, Br or I; R and R' are independently C1-C5 straight-chain alkyl or alkyl with free branched-chain. With the method provided by the invention, 1,3-butadiene is highly selectively converted into 1,5,9-cyclododecatriene, and is especially highly selectively converted into trans,trans,cis-1,5,9-cyclododecatriene. Through refining, fine 1,5,9-cyclododecatriene with purity higher than 99% can be obtained. Therefore, the method has important industrial application prospect.
priorityDate 2012-11-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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