http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103193912-B
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_65682d3e437c225d79b93953b4b26392 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02E10-549 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F2-38 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F120-36 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F8-48 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/H01L51-46 |
filingDate | 2013-04-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2015-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2eb9ab2b5a98c3d848b717235f8ca1b2 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_502f42b9d145f738fc5dca5d33b85830 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_60ef59ceb377385437dc3c9ccd84e07a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_65fa7e1dcdd203c079c22954fcacc26e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_efb9fea17f875213e2ca3542bafcabc9 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d13e524f027e192dedc2fb9067db81e3 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_7fd286378327b6ca0494766e0d5eb825 |
publicationDate | 2015-01-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-103193912-B |
titleOfInvention | Copolymer containing zinc-phthalocyanine group on side chain and preparation method thereof |
abstract | The invention discloses a copolymer containing a zinc-phthalocyanine group on a side chain and a preparation method thereof. The preparation method of the copolymer combines RAFT (reversible addition-fragmentation chain transfer) and a phthalocyanin annulation method for the first time to prepare the copolymer containing a zinc-phthalocyanine group on a side chain, and comprises the following steps of: on the presence of an initiator and a chain transfer agent, performing RAFT polymerization on a monomer methacrylic acid-6-(3,4-dicyanophenoxy)caprolactone to obtain a polymer PMADCE (polymethyl acrylic acid-6-(3,4-dicyanophenoxy)caprolactone) containing a phthalonitrile functional group on a side chain; and using the phthalonitrile functional group on the side chain of the PMADCE as a reaction point to perform phthalocyanin annulation with 4-(octyloxy)phthalonitrile in the presence of a heat-sensitive catalyst and zinc acetate so as to obtain a polymer PMADCE-ZnPc containing the zinc-phthalocyanine group on the side chain. The preparation method is few in step, simple, feasible, convenient in purification process, mild in reaction condition, controllable in process and high in conversion rate; and the PMADCE-ZnPc prepared by the method has good solubility and phthalocyanin functionality, can be used as a photoelectric material, and has good application prospects in solar cells, sensors and information storage. |
priorityDate | 2013-04-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 80.