http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103113181-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1e74277852f1aae0a3ff13f59a65456d |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C13-465 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C13-15 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C2-86 |
| filingDate | 2013-01-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_06b105bbec406cb64b35f105ad222698 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2de8e033ebca7b28f2ded0b67865f99f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ec070e0bb2fe3fcbda709b3e4a0f8cab |
| publicationDate | 2013-05-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-103113181-A |
| titleOfInvention | A kind of synthetic method of multi-substituted cyclopentadiene |
| abstract | The present invention relates to a method for synthesizing multi-substituted cyclopentadiene derivatives. Steps: a) react alkynes represented by formula I with low-valent zirconocene compounds in ether solvents, and then add formula The alkyne shown in II continues to react, and the reaction temperature of the above process is between 25°C and the boiling point of the ether solvent; b) adding diiodomethane, cuprous chloride and ligands shown in formula III to the step a ) in the reaction solution, the reaction temperature is between the freezing point of the ether solvent and -20°C; the temperature is raised to the boiling point of the ether solvent; c) the extraction reaction solution is post-treated to obtain the tetrasubstituted cyclopentadiene shown in formula IV ; The reaction formula is as follows: The invention has high yield, easy-to-obtain raw materials and high separation yield. |
| priorityDate | 2013-01-31-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
| Predicate | Subject |
|---|---|
| isDiscussedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/substance/SID465669135 http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID141323747 |
Total number of triples: 16.