http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-102976892-B
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_7a8dbd57d579ae21e96209d1f3c25a32 http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_be2c55a9de09e08e3404c0a5a1ae4dc7 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-149 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C31-08 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J29-76 |
filingDate | 2012-11-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2014-12-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_072c4b959ef301083b075103df082c7e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3317da52930f193813cd589d127bafda http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3d740aff8bfdc5bd51b200e940aedb2f http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b7affd221f9996222fc379da24a48442 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_4bf9b7f02f28e77f89ec0b1843758e7e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e84d0f486120558c407a8535673e6c4a http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_0cfbb80cce931e7deef4af9d6ba83d64 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_90dee46203aebe1d78af3c547d224de5 |
publicationDate | 2014-12-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | CN-102976892-B |
titleOfInvention | Method for preparing ethanol through acetic ester hydrogenation |
abstract | The invention relates to a method for preparing ethanol through acetic ester hydrogenation. The method performs an acetic ester hydrogenation reaction to generate ethanol under the conditions of certain temperature, pressure, hydrogen/ester molar ratio and hydrogen circulation in a fixed-bed reactor filled with a copper-based catalyst, wherein in the copper-based catalyst, a mesoporous molecular sieve MCM-41 is used as a carrier, copper is used as an active component, and the oxide of at least one element of La and Ce is used as an auxiliary; and the MCM-41 accounts for 40-90% of the catalyst by weight, the active component copper accounts for 10-50% of the catalyst by weight, and the auxiliary accounts for 0.1-20% of the catalyst by weight. According to the method for preparing ethanol through acetic ester hydrogenation, provided by the invention, when the reaction temperature is 220 DEG C, the reaction pressure is 3MPa, the hydrogen/ester molar ratio is 30 and the mass airspeed of acetic ester is 2h<-1>, the conversion rate of acetic ester is 98.5%, and the ethanol selectivity is as high as 99.6%, thereby showing extremely high hydrogenation activity, selectivity and stability. |
priorityDate | 2012-11-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 56.