http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-102911191-B

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filingDate 2012-10-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2015-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_63e2877f3cbe52b41daea59dbfacd1cd
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publicationDate 2015-05-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-102911191-B
titleOfInvention Preparation method for ethanol 2-hydroxyl naphthaldehyde thiosemicarbazone o-phenanthroline metal complex
abstract The invention discloses a preparation method for an ethanol 2-hydroxyl naphthaldehyde thiosemicarbazone o-phenanthroline metal complex, and belongs to the field of bioinorganic chemistry. M is Cu, Zn, Ni or Co. The preparation method comprises the steps of: dissolving thiosemicarbazide in a hot ethanol/water mixed solvent, and carrying out heating and reflowing reaction an ethanol/water solution of 2-hydroxyl naphthaldehyde under a stirring action to obtain 2-hydroxyl naphthaldehyde thiosemicarbazone (H2L); and dissolving the 2-hydroxyl naphthaldehyde thiosemicarbazone (H2L) in a hot ethanol/water mixed solvent, adding an absolute ethanol solution of acetate under the stirring action, dropwise adding an absolute ethanol solution of 1,10-phenanthroline (o-phenanthroline) at the same time, carrying out stirring and heating reaction, cooling and filtering to separate out a solid, namely the ethanol 2-hydroxyl naphthaldehyde thiosemicarbazone o-phenanthroline metal complex. Raw materials are easily available and cheap, and the preparation method is simple and easy to implement and is convenient for industrial production.
priorityDate 2012-10-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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