| abstract |
The invention relates to a polymerization method for preparing rare earth isoprene rubber, which adopts at least three reactors which are in series connection to conduct a solution polymerization reaction of an isoprene monomer, wherein a first reactor is an annular tube reactor which adopts isothermal operation, a following reactor is a continuous stirrer tank reactor which adopts heat insulation operation. By means of the method, the cis-form-1,4-configuration content of obtained gathering rare earth isoprene rubber can be high as 98wt%, the number-average molar mass can reach over 0.4 million, and molecular weight distribution coefficient is smaller than 3. |