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classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F15-00
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filingDate 2011-09-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2014-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3e6668914d9245ee54ce35abaa0fc5b4
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_161aa83e375e7c44883a72ef033cdfe3
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publicationDate 2014-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-102408450-B
titleOfInvention Preparation method of iridium complex-containing phosphorescence material and its application in cobalt ion detection
abstract Belonging to the technical field of photoelectric phosphorescence materials, the invention discloses a preparation method of an iridium complex-containing phosphorescence material and its application in cobalt ion detection. With a general structural formula as shown in formula I, the iridium complex-containing phosphorescence material of the invention can be used for Co<2+> detection and comprises a main ligand and an auxiliary ligand, wherein, the main ligand is a derivative of 3, 4-disubstituted cinnoline, and the auxiliary ligand is a derivative of 15 crown-5 ether dipyridine. By means of the influence of Co<2+> on photo-physical and sensing properties of the iridium complex, the phosphorescence chemical sensor can observe the change of its phosphorescence emission spectrum so as to reach the Co<2+> detection purpose. The phosphorescence chemical sensor of the invention has the advantages of rapid phosphorescence response speed, easy differentiation from a fluorescence background, large range, high identification sensitivity to Co<2+>, good stability, and applicability for Co<2+> detection in various environments, and small interference from other positive ions, etc. Formula I is shown as the following.
priorityDate 2011-09-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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