Predicate |
Object |
classificationCPCAdditional |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J21-005 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y02P20-584 |
classificationCPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-1014 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-006 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J35-002 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C45-73 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-6522 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J38-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J23-60 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-031 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-0201 |
classificationIPCInventive |
http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-73 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C1-24 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J23-652 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C29-145 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C31-10 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C49-203 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C15-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C45-74 |
filingDate |
2011-04-21-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate |
2016-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate |
2016-01-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber |
CN-102371153-B |
titleOfInvention |
The synthesis of the nano Pd catalyst of nanocrystal chromous acid zinc load and application |
abstract |
The present invention relates to synthesis and the application of the nano Pd catalyst of new nanocrystal chromous acid zinc load.This catalyst comprises platinum group metal, metal oxide and nano zine oxide.Synthesize the carbon monoxide-olefin polymeric of several Metal Supported based on nanocrystal zinc oxide, and by X-ray powder diffraction (XRD), carbon dioxide temperature programmed desorption (COn 2 tPD) and the N2 adsorption of-196 DEG C characterize.From different oxide as Crn 2 on 3 , CrOn 3 , MgO and γ-Aln 2 on 3 the nano-ZnO of the Pd-load of mixing demonstrates high catalytic activity in gas phase process under hydrogen stream in condensation of acetone.This reaction relates to the Acid-Base coupling of acetone to form Mesityl oxide, then generates methyl iso-butyl ketone (MIBK) (MIBK) by its hydrogenation.New catalyst 1wt%n-Pd/n-ZnCr is used during the gas-phase reaction of MIBK production periodn 2 on 4 .300 ~ 350 DEG C time 66% ~ 77% acetone conversion under the selective of MIBK be 70% ~ 72%.DIBK (DIBK) is main accessory substance, and the overall selectivity of MIBK+DIBK is up to 88%.The catalyst of preparation shows stable activity and the Ke Chong Fu Long phase uses. |
isCitedBy |
http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9511353-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9511350-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9511355-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9555400-B2 http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-9545626-B2 |
priorityDate |
2010-08-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type |
http://data.epo.org/linked-data/def/patent/Publication |