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filingDate 2011-10-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2013-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2013-09-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-102354755-B
titleOfInvention Preparation method of strontium and barium activated lithium iron phosphate positive pole material
abstract The invention discloses a preparation method of a strontium and barium activated lithium iron phosphate positive pole material. The preparation method is characterized by comprising the following steps: mixing a lithium source, an iron source, a phosphate radical source, and a strontium source utilized as a raw material according to the ratio of 1:(0.00002-0.00005):(0.0003-0.003):1:1; in an absolute ethyl alcohol medium, carrying out high-speed ball-milling for 20 hours at the rotation rate of 200r/mimn and drying at the temperature of 105-120 DEG C, thereby obtaining a front body, and placing the drying obtained front body in a high temperature furnace; and carrying out high-temperature calcination for 24 hours at 500-750 DEG C in a common pure nitrogen atmosphere on to obtain the strontium, barium activating lithium iron phosphate positive pole material. According to the invention, strontium and the barium are replaced because of the doping, the feature and the particle diameter of a product are effectively controlled, thereby obtaining a stable lithium iron phosphate compound, the crystal lattice of the lithium iron phosphate compound is activated, the lithium ion diffusion coefficient is improved, and the loading capacity achieves 160.52 m A h/g in the first time; a charge-discharge platform relative to lithium electrode potential is around 3.5V, the initial discharge capacity exceeds 168 m A h/g, and the capacity decays around 1.2% after the charging and discharging are circled for100 times; compared with the unmixed LiFePO4 contrast embodiment, the specific capacity and the cyclical stability are greatly improved.
priorityDate 2011-10-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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