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publicationDate 2009-07-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-101472864-A
titleOfInvention A process for selectively hydrogenating butadiene in an C4 olefin stream containing a catalyst poison with the simultaneous isomerization of 1-butene to 2-butene
abstract A process for selectively hydrogenating butadiene that is contained in a C4 stream having a concentration of a catalyst poison and C4 olefins, including 1-butene, and further the process provides for the substantial isomerization of the 1-butene to 2-butene of the C4 olefin stream, wherein the process comprises contacting, under suitable process conditions, the C4 stream with a poison tolerant catalyst comprising an alumina support material and partially sulfided nickel on the alumina support material at a concentration in the range of from 5 to 40 weight percent nickel, and yielding a product having a minimal butadiene concentration and a reduced concentration 1-butene.
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