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filingDate 2007-03-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ef9de2c04befb4d0939d2e919078f582
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publicationDate 2009-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CN-101400637-A
titleOfInvention Process for production of adamantyl (mono- or poly-)acetate, and process for production of adamantyl (mono- or poly-)ethanol using the same
abstract The object is to provide: a process for producing a substituted or unsubstituted adamantyl (mono- or poly-)acetate in a high yield, wherein the production of impurities is remarkably reduced in the process; and a process for producing a substituted or unsubstituted adamantyl (mono- or poly-)ethanol by reducing the adamantyl (mono- or poly-)acetate. Disclosed is a process for producing an adamantyl (mono- or poly-)acetate represented by the general formula (2), comprising the steps of: dropwisely adding sulfuric acid having a concentration of 80 to 97 mass% to a mixture of an adamantane compound represented by the general formula (1) and a halogenated vinylidene while keeping the temperature of the mixture at 0 to 15 DEG C, thereby causing the reaction of the adamantane compound with the halogenated vinylidene; and contacting the reaction solution with water. Also disclosed is a process for producing an adamantyl (mono- or poly-)ethanol represented by the general formula (3), comprising the step of reducing the adamantyl (mono- or poly-)acetate. In the formulae, R represents an alkyl group or the like, X represents a hydroxyl group or a halogen atom, and m and n independently represent a specific integer.
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