http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-101250203-B
Outgoing Links
| Predicate | Object |
|---|---|
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F19-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F17-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F5-02 |
| filingDate | 2008-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| grantDate | 2011-11-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 2011-11-30-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | CN-101250203-B |
| titleOfInvention | Method for preparing thio-1,2-dicarbo-closo-dodecacarborane organic derivatives and product thereof |
| abstract | A method for preparing thio-1, 2-dicarbo-closo-dodecarborane (12) organic derivative comprises adding n-butyllithium into the ether solution of 1, 2-C2B10H12, mixing for 0.5-2h, adding sulfur, mixing for 1-3h, to obtain Li2S2C2B10H10, at low temperature, adding tetrahydrofuran solution of metal compound into the ether solution of Li2E2C2B10H10 (1:1), at low temperature, mixing for 1-3h, naturalling increasing temperature to room temperature, mixing for 2-12h, separating, evaporating out solvent to obtain the plane four-coordination metal compound 1 of thio-1, 2-dicarbo-closo-dodecarborane (12)complex, wherein the metal compound belongs to VIII group. The metal complex 1 of plane four-sulfur coordination and alkyne can be dissolved in organic solvent to be reacted for 1-24h at -20DEG C to 110DEG C, to obtain thio-1, 2-dicarbo-closo-dodecarborane (12) organic derivative. The invention has simple process, which can prepare Fc(CCH)(S2C2B10H10), [(FcC(CH2)S)]2C2B10H10, Ph(CCH)(S2C2B10H10) and (MeOCOCHCHS)2C2B10H10. |
| priorityDate | 2008-03-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
| Predicate | Subject |
|---|---|
| isDiscussedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID15658 http://rdf.ncbi.nlm.nih.gov/pubchem/substance/SID414878155 |
Total number of triples: 13.