http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CH-516570-A

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D251-68
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D251-68
filingDate 1967-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_1fa772d137a495e78e2a1913e2ce436b
publicationDate 1971-12-15-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber CH-516570-A
titleOfInvention Process for the preparation of asymmetric bis-triazinylamino-stilbenes
abstract The stilbenes have formula:- in which one X = H and the other = Cl in the 2-, 3- or 4-position, Y = methylamino, dimethylamino, beta-hydroxyethylamino, N-methyl-N-beta-hydroxyethylamino or morpholino radical and Z = a cation forming atom or gp. . They are prepared in 2 ways:- (I) by reacting cyanuric chloride/bromide, in any desired order, with (a) 4,4'-diaminostilbene-2,2'-disulphonic acid or salt (b) methylamine, dimethylamine, -hydroxyethylamine, N-methyl-N-hydroxyethylamine or morpholine, (c) aminobenzene and (d) chloroaminobenzene, using, per mol. (a), 2 mols. cyanuric halide, 2 mols. (b) and 2 mols. of a mixture of (c) and (d) pref. in molar proportion 1:1; and (II) by reacting, in a 1st. reaction sequence, 1 mol. cyanuric halide in any desired order with 1 mol. (a), 1 mol. (b) and 1 mol. (c) or (d). The NO2 gp. in the resulting product is reduced and, in a 2nd. reaction sequence, 1 mol. cyanuric halide is reacted, in any desired order, with 1 mol. of the resulting amino cpd. 1 mol. (b) and 1 mol. (c) or (d), (d) being used in the 2nd. reaction sequence when (c) is used in the 1st. and vice versa.
priorityDate 1967-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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